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High-quality industrial n-type silicon wafers with an efficiency of over 23% for Si heterojunction solar

Fanying MENG,Jinning LIU,Leilei SHEN,Jianhua SHI,Anjun HAN,Liping ZHANG,Yucheng LIU,Jian YU,Junkai ZHANG,Rui ZHOU,Zhengxin LIU

《能源前沿(英文)》 2017年 第11卷 第1期   页码 78-84 doi: 10.1007/s11708-016-0435-5

摘要: n-type CZ-Si wafers featuring longer minority carrier lifetime and higher tolerance of certain metal contamination can offer one of the best Si-based solar cells. In this study, Si heterojuction (SHJ) solar cells which was fabricated with different wafers in the top, middle and tail positions of the ingot, exhibited a stable high efficiency of>22% in spite of the various profiles of the resistivity and lifetime, which demonstrated the high material utilization of n-type ingot. In addition, for effectively converting the sunlight into electrical power, the pyramid size, pyramid density and roughness of surface of the Cz-Si wafer were investigated by scanning electron microscope (SEM) and transmission electron microscope (TEM). Furthermore, the dependence of SHJ solar cell open-circuit voltage on the surface topography was discussed, which indicated that the uniformity of surface pyramid helps to improve the open-circuit voltage and conversion efficiency. Moreover, the simulation revealed that the highest efficiency of the SHJ solar cell could be achieved by the wafer with a thickness of 100 µm. Fortunately, over 23% of the conversion efficiency of the SHJ solar cell with a wafer thickness of 100 µm was obtained based on the systematic optimization of cell fabrication process in the pilot production line. Evidently, the large availability of both n-type ingot and thinner wafer strongly supported the lower cost fabrication of high efficiency SHJ solar cell.

关键词: n-type Cz-Si     thinner wafer     surface texture     high efficiency     SHJ solar cell    

利用三元合金保护和催化的硅光阳极与廉价硅太阳能电池相结合实现12.0%的太阳能制氢效率 Article

何凌云, 洪欣, 王亦清, 邢众航, 耿嘉峰, 郭鹏慧, 苏进展, 沈少华

《工程(英文)》 2023年 第25卷 第6期   页码 128-137 doi: 10.1016/j.eng.2022.03.023

摘要:

n型硅(n-Si)表面在水溶液中容易被氧化和钝化,导致其在光电化学(PEC)分解水的析氧反应(OER)动力学缓慢。本工作通过欠电位沉积成功地在p+n-Si基底上电沉积了三金属Ni0.9Fe0.05Co0.05保护层。制备的Ni0.9Fe0.05Co0.05/p+n-Si光阳极具有优异的稳定性和PEC水氧化活性,具有相对低的OER起始电位(相对于可逆氢电极电势(RHE)仅为0.938 V),并且在1.23 V vs.RHE电位时具有较高的光电流密度(33.1 mA∙cm-2),显著优于Ni/p+n-Si光阳极。工作证明了Fe在Ni层的掺杂会在Ni0.9Fe0.05Co0.05/p+n-Si界面处产生较大的能带弯曲,促进界面电荷分离。

关键词: n-Si     光阳极     水分解     光伏/光电化学器件    

Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting toward

《能源前沿(英文)》 doi: 10.1007/s11708-023-0881-9

摘要: Sunlight-powered water splitting presents a promising strategy for converting intermittent and virtually unlimited solar energy into energy-dense and storable green hydrogen. Since the pioneering discovery by Honda and Fujishima, considerable efforts have been made in this research area. Among various materials developed, Ga(X)N/Si (X = In, Ge, Mg, etc.) nanoarchitecture has emerged as a disruptive semiconductor platform to split water toward hydrogen by sunlight. This paper introduces the characteristics, properties, and growth/synthesis/fabrication methods of Ga(X)N/Si nanoarchitecture, primarily focusing on explaining the suitability as an ideal platform for sunlight-powered water splitting toward green hydrogen fuel. In addition, it exclusively summarizes the recent progress and development of Ga(X)N/Si nanoarchitecture for photocatalytic and photoelectrochemical water splitting. Moreover, it describes the challenges and prospects of artificial photosynthesis integrated device and system using Ga(X)N/Si nanoarchitectures for solar water splitting toward hydrogen.

关键词: Ga(X)N/Si nanoarchitecture     artificial photosynthesis     water splitting     solar toward hydrogen    

Nitrate removal to its fate in wetland mesocosm filled with sponge iron: Impact of influent COD/N ratio

Zhihao Si, Xinshan Song, Xin Cao, Yuhui Wang, Yifei Wang, Yufeng Zhao, Xiaoyan Ge, Awet Arefe Tesfahunegn

《环境科学与工程前沿(英文)》 2020年 第14卷 第1期 doi: 10.1007/s11783-019-1183-7

摘要: CW-Fe allowed a high-performance of NO3‒-N removal at the COD/N ratio of 0. Higher COD/N resulted in lower chem-denitrification and higher bio-denitrification. The application of s-Fe0 contributed to TIN removal in wetland mesocosm. s-Fe0 changed the main denitrifiers in wetland mesocosm. Sponge iron (s-Fe0) is a porous metal with the potential to be an electron donor for denitrification. This study aims to evaluate the feasibility of using s-Fe0 as the substrate of wetland mesocosms. Here, wetland mesocosms with the addition of s-Fe0 particles (CW-Fe) and a blank control group (CW-CK) were established. The NO3‒-N reduction property and water quality parameters (pH, DO, and ORP) were examined at three COD/N ratios (0, 5, and 10). Results showed that the NO3‒-N removal efficiencies were significantly increased by 6.6 to 58.9% in the presence of s-Fe0. NH4+-N was mainly produced by chemical denitrification, and approximately 50% of the NO3‒-N was reduced to NH4+-N, at the COD/ratio of 0. An increase of the influent COD/N ratio resulted in lower chemical denitrification and higher bio-denitrification. Although chemical denitrification mediated by s-Fe0 led to an accumulation of NH4+-N at COD/N ratios of 0 and 5, the TIN removal efficiencies increased by 4.5%‒12.4%. Moreover, the effluent pH, DO, and ORP values showed a significant negative correlation with total Fe and Fe (II) (P<0.01). High-throughput sequencing analysis indicated that Trichococcus (77.2%) was the most abundant microorganism in the CW-Fe mesocosm, while Thauera, Zoogloea, and Herbaspirillum were the primary denitrifying bacteria. The denitrifiers, Simplicispira, Dechloromonas, and Denitratisoma, were the dominant bacteria for CW-CK. This study provides a valuable method and an improved understanding of NO3‒-N reduction characteristics of s-Fe0 in a wetland mesocosm.

关键词: Sponge iron     Wetland mesocosm     Electronic donor     Denitrification     COD/N ratio    

Predicting beach profile evolution with group method data handling-type neural networks on beaches with

MEHRDAD, N. ABEDIMAHZOON, N. ASADOLLAHI

《结构与土木工程前沿(英文)》 2013年 第7卷 第2期   页码 117-126 doi: 10.1007/s11709-013-0205-y

摘要: A major goal of coastal engineering is to develop models for the reliable prediction of short- and long-term near shore evolution. The most successful coastal models are numerical models, which allow flexibility in the choice of initial and boundary conditions. In the present study, evolutionary algorithms (EAs) are employed for multi-objective Pareto optimum design of group method data handling (GMDH)-type neural networks that have been used for bed evolution modeling in the surf zone for reflective beaches, based on the irregular wave experiments performed at the Hydraulic Laboratory of Imperial College (London, UK). The input parameters used for such modeling are significant wave height, wave period, wave action duration, reflection coefficient, distance from shoreline and sand size. In this way, EAs with an encoding scheme are presented for evolutionary design of the generalized GMDH-type neural networks, in which the connectivity configurations in such networks are not limited to adjacent layers. Also, multi-objective EAs with a diversity preserving mechanism are used for Pareto optimization of such GMDH-type neural networks. The most important objectives of GMDH-type neural networks that are considered in this study are training error (TE), prediction error (PE), and number of neurons ( ). Different pairs of these objective functions are selected for two-objective optimization processes. Therefore, optimal Pareto fronts of such models are obtained in each case, which exhibit the trade-offs between the corresponding pair of the objectives and, thus, provide different non-dominated optimal choices of GMDH-type neural network model for beach profile evolution. The results showed that the present model has been successfully used to optimally prediction of beach profile evolution on beaches with seawalls.

关键词: beach profile evolution     genetic algorithms     group method of data handling     Pareto     reflective beaches    

结构功能一体化的高性能陶瓷材料的研究与开发

江东亮

《中国工程科学》 2003年 第5卷 第2期   页码 35-39

摘要: 复合化、低成本制备等要求出发, 并就现有高性能陶瓷材料的基本性能和材料制备工艺上的优缺点进行了分析;简要介绍了碳化硅(SiC)陶瓷、 添加Nd的钇铝石榴子石(Nd-YAG)陶瓷、掺有稀土的氮化硅(RE-Si3N4)陶瓷等几种具有结构和功能一体化高性能陶瓷材料的优良性能,可能的应用以及目前存在的问题,特别是在基础研究和制备科学上今后应予以关注的方面。

关键词: 结构和功能一体化     高性能陶瓷     碳化硅     Nd-YAG     RE-Si3N4    

Kinematic calibration of precise 6-DOF stewart platform-type positioning systems for radio telescope

HERNáNDEZ, Marco CECCARELLI, Carlos LóPEZ-CAJúN, Alejandro GARCíA

《机械工程前沿(英文)》 2013年 第8卷 第3期   页码 252-260 doi: 10.1007/s11465-013-0249-7

摘要:

The pose accuracy of a parallel robot is a function of the mobile platform posture. Thus, there is no a single value of the robot’s accuracy. In this paper, two novel methods for estimating the accuracy of parallel robots are presented. In the first method, the pose accuracy estimation is calculated by considering the propagation of each error, i.e., error variations are considered as a function of the actuator’s stroke. In the second method, it is considered that each actuator has a constant error at any stroke. Both methods can predict pose accuracy of precise robots at design stages, and/or can reduce calibration time of existing robots. An example of a six degree-of-freedom parallel manipulator is included to show the application of the proposed methods.

关键词: pose errors     error estimation     parallel robot     radio telescopes    

Mathematical model and manufacture programming of loxodromic-type normal circular-arc spiral bevel gear

Zhenyun DUAN, Houjun CHEN, Zhilan JU, Jian LIU

《机械工程前沿(英文)》 2012年 第7卷 第3期   页码 312-321 doi: 10.1007/s11465-012-0308-5

摘要:

In this paper, loxodromic-type normal circular-arc spiral bevel gear is proposed as a novel application of the circular-arc tooth profile at the gear transmission with intersecting axes. Based on the principle of molding-surface conjugation, the study develops a mathematical model for the tooth alignment curve and the computational flow at the design stage to enable the generation of the tooth surface. Machining of the tooth surface is then carried out to determine the interference-free tool path of the numerical control (NC). Moreover, a pair of loxodromic-type normal circular-arc spiral bevel gears is manufactured on computer numerical control (CNC) machine tools. The proposed theory and method are experimentally investigated, and the obtained results primarily reflect the superior performance of the proposed novel gear.

关键词: loxodrome     circular-arc tooth profile     Wildhaber-Novikov (W-N) gear     spiral bevel gear    

具有异构时延的多智能体系统的领导-跟随同步 Research Articles

Branislav REH罧, Volodymyr LYNNYK

《信息与电子工程前沿(英文)》 2021年 第22卷 第1期   页码 1-140 doi: 10.1631/FITEE.2000207

摘要: 提出一种由时滞线性智能体组成的多智能体系统的领导-跟随同步算法。各智能体中存在的不同时滞会导致不收敛于零的同步误差。但是,可限制误差范数并给出误差边界。利用线性矩阵不等式对主要结果进行验证,且该问题的规模与智能体数量无关。通过案例对结果进行说明,强调稳定误差是由异构延迟引起的事实,并验证该算法在一定误差范围内有实现同步的能力。

关键词: 多智能体系统;时滞;线性矩阵不等式    

Plasma enhanced chemical vapor deposition of excellent a-Si:H passivation layers for a-Si:H/c-Si heterojunction

Lei ZHAO,Wenbin ZHANG,Jingwei CHEN,Hongwei DIAO,Qi WANG,Wenjing WANG

《能源前沿(英文)》 2017年 第11卷 第1期   页码 85-91 doi: 10.1007/s11708-016-0437-3

摘要: The intrinsic a-Si:H passivation layer inserted between the doped a-Si:H layer and the c-Si substrate is very crucial for improving the performance of the a-Si:H/c-Si heterojunction (SHJ) solar cell. The passivation performance of the a-Si:H layer is strongly dependent on its microstructure. Usually, the compact a-Si:H deposited near the transition from the amorphous phase to the nanocrystalline phase by plasma enhanced chemical vapor deposition (PECVD) can provide excellent passivation. However, at the low deposition pressure and low deposition power, such an a-Si:H layer can be only prepared in a narrow region. The deposition condition must be controlled very carefully. In this paper, intrinsic a-Si:H layers were prepared on n-type Cz c-Si substrates by 27.12 MHz PECVD at a high deposition pressure and high deposition power. The corresponding passivation performance on c-Si was investigated by minority carrier lifetime measurement. It was found that an excellent a-Si:H passivation layer could be obtained in a very wide deposition pressure and power region. Such wide process window would be very beneficial for improving the uniformity and the yield for the solar cell fabrication. The a-Si:H layer microstructure was further investigated by Raman and Fourier transform infrared (FTIR) spectroscopy characterization. The correlation between the microstructure and the passivation performance was revealed. According to the above findings, the a-Si:H passivation performance was optimized more elaborately. Finally, a large-area SHJ solar cell with an efficiency of 22.25% was fabricated on the commercial 156 mm pseudo-square n-type Cz c-Si substrate with the open-circuit voltage ( ) of up to 0.732 V.

关键词: PECVD     high pressure and high power     a-Si:H microstructure     passivation     heterojunction solar cell    

Analysis of the double-layer α-Si:H emitter with different doping concentrations for α-Si:H/c-Si heterojunction

Haibin HUANG,Gangyu TIAN,Tao WANG,Chao GAO,Jiren YUAN,Zhihao YUE,Lang ZHOU

《能源前沿(英文)》 2017年 第11卷 第1期   页码 92-95 doi: 10.1007/s11708-016-0432-8

摘要: Double-layer emitters with different doping concentrations (DLE) have been designed and prepared for amorphous silicon/crystalline silicon (α-Si:H/c-Si) heterojunction solar cells. Compared with the traditional single layer emitter, both the experiment and the simulation (AFORS-HET, http://www.paper.edu.cn/html/releasepaper/2014/04/282/) prove that the double-layer emitter increases the short circuit current of the cells significantly. Based on the quantum efficiency (QE) results and the current-voltage-temperature analysis, the mechanism for the experimental results above has been investigated. The possible reasons for the increased current include the enhancement of the QE in the short wavelength range, the increase of the tunneling probability of the current transport and the decrease of the activation energy of the emitter layers.

关键词: double-layer emitter     α-Si:H/c-Si heterojunction solar cell     short circuit current     quantum efficiency     current-voltage-temperature    

基于正交质谱的N-糖组谱揭示哈夫病潜在病原学 Article

刘思, 刘圆圆, 林佳静, 刘笔锋, 何振宇, 吴晓旻, 刘欣

《工程(英文)》 2023年 第26卷 第7期   页码 63-73 doi: 10.1016/j.eng.2022.09.012

摘要: N-糖组的剖析将促进破译疾病的分子机制,而HD相关的糖基化从未被探索过。本文中,采用基于高通量的正交质谱对HD中血清和血清衍生的IgG的N-糖组谱进行了表征。数据显示,HD与总血清糖蛋白的核心岩藻糖基化和单半乳糖醇化升高有关。本研究表明差异化IgG N-糖基化与HD的关联,为这种罕见疾病的病因提供了新的见解。

关键词: 哈夫病     全血清     IgG抗体     糖基化     疾病病原学    

Preparation and lithium storage performances of g-C

Zhengxu BIAN, Zehua TANG, Jinfeng XIE, Junhao ZHANG, Xingmei GUO, Yuanjun LIU, Aihua YUAN, Feng ZHANG, Qinghong KONG

《能源前沿(英文)》 2020年 第14卷 第4期   页码 759-766 doi: 10.1007/s11708-020-0810-0

摘要: As the anode material of lithium-ion battery, silicon-based materials have a high theoretical capacity, but their volume changes greatly in the charging and discharging process. To ameliorate the volume expansion issue of silicon-based anode materials, g-C N /Si nanocomposites are prepared by using the magnesium thermal reduction technique. It is well known that g-C N /Si nanocomposites can not only improve the electronic transmission ability, but also ameliorate the physical properties of the material for adapting the stress and strain caused by the volume expansion of silicon in the lithiation and delithiation process. When g-C N /Si electrode is evaluated, the initial discharge capacity of g-C N /Si nanocomposites is as high as 1033.3 mAh/g at 0.1 A/g, and its reversible capacity is maintained at 548 mAh/g after 400 cycles. Meanwhile, the improved rate capability is achieved with a relatively high reversible specific capacity of 218 mAh/g at 2.0 A/g. The superior lithium storage performances benefit from the unique g-C N /Si nanostructure, which improves electroconductivity, reduces volume expansion, and accelerates lithium-ion transmission compared to pure silicon.

关键词: magnesium thermal reduction     g-C3N4/Si nanocomposites     volume expansion     electroconductivity     lithium-ion battery    

Stability and dynamics of rotor system with 45° slant crack on shaft

Yanli LIN, Xiaohui SI, Fulei CHU

《机械工程前沿(英文)》 2011年 第6卷 第2期   页码 203-213 doi: 10.1007/s11465-011-0131-4

摘要:

Crack on a shaft is one of the common damages in a rotor system. In this paper, transverse vibrations are calculated to compare the influences of transverse crack and slant crack on the rotor system. Results show that the vibration amplitude of the rotor system with a 45° slant crack on the shaft is larger than that with a transverse crack when the two types of crack have the same depth and the rotor system runs in the same condition. Stability and dynamic characteristics of the rotor system with a 45° slant crack on the shaft under torsional excitation are analyzed by considering opening and closing of the crack. It is shown that the instability of the transverse vibration of the rotor system increases with increasing difference between the bending stiffness in two main directions, and the vibration is stable when the two bending stiffness are identical. The spectrum analysis of the steady-state response reveals that the gravity and the eccentricity produce different frequency components, and when the two bending stiffness are identical, the multiple frequency components of the torsional excitation disappear. Further investigation shows that the vibration amplitudes in combined frequencies increase rapidly in transversal, torsional, and axial vibration with increasing slant crack depth. The results are helpful for the understanding the dynamic behavior of a rotor system with a slant crack on a shaft and can be used for the detection of the slant crack on a shaft.

关键词: rotor dynamics     slant crack     stability     torsional excitation     open and close    

New practice in semaglutide on type-2 diabetes and obesity: clinical evidence and expectation

《医学前沿(英文)》 2022年 第16卷 第1期   页码 17-24 doi: 10.1007/s11684-021-0873-2

摘要: Obesity is an important risk factor of type 2 diabetes (T2D), which has become an important factor threatening human health. However, no perfect drug choice for obesity exists. Semaglutide is a kind of human glucagon-like peptide-1 (GLP-1) analog that promotes insulin secretion while inhibiting glucagon secretion through a glucose concentration-dependent mechanism. GLP-1 can also delay stomach emptying and suppress appetite to help lose weight. This review summarizes clinical evidence of the semaglutide effect on T2D and obesity and establishes expectations on future clinical trials for obesity treatment.

关键词: semaglutide     type 2 diabetes     obesity    

标题 作者 时间 类型 操作

High-quality industrial n-type silicon wafers with an efficiency of over 23% for Si heterojunction solar

Fanying MENG,Jinning LIU,Leilei SHEN,Jianhua SHI,Anjun HAN,Liping ZHANG,Yucheng LIU,Jian YU,Junkai ZHANG,Rui ZHOU,Zhengxin LIU

期刊论文

利用三元合金保护和催化的硅光阳极与廉价硅太阳能电池相结合实现12.0%的太阳能制氢效率

何凌云, 洪欣, 王亦清, 邢众航, 耿嘉峰, 郭鹏慧, 苏进展, 沈少华

期刊论文

Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting toward

期刊论文

Nitrate removal to its fate in wetland mesocosm filled with sponge iron: Impact of influent COD/N ratio

Zhihao Si, Xinshan Song, Xin Cao, Yuhui Wang, Yifei Wang, Yufeng Zhao, Xiaoyan Ge, Awet Arefe Tesfahunegn

期刊论文

Predicting beach profile evolution with group method data handling-type neural networks on beaches with

MEHRDAD, N. ABEDIMAHZOON, N. ASADOLLAHI

期刊论文

结构功能一体化的高性能陶瓷材料的研究与开发

江东亮

期刊论文

Kinematic calibration of precise 6-DOF stewart platform-type positioning systems for radio telescope

HERNáNDEZ, Marco CECCARELLI, Carlos LóPEZ-CAJúN, Alejandro GARCíA

期刊论文

Mathematical model and manufacture programming of loxodromic-type normal circular-arc spiral bevel gear

Zhenyun DUAN, Houjun CHEN, Zhilan JU, Jian LIU

期刊论文

具有异构时延的多智能体系统的领导-跟随同步

Branislav REH罧, Volodymyr LYNNYK

期刊论文

Plasma enhanced chemical vapor deposition of excellent a-Si:H passivation layers for a-Si:H/c-Si heterojunction

Lei ZHAO,Wenbin ZHANG,Jingwei CHEN,Hongwei DIAO,Qi WANG,Wenjing WANG

期刊论文

Analysis of the double-layer α-Si:H emitter with different doping concentrations for α-Si:H/c-Si heterojunction

Haibin HUANG,Gangyu TIAN,Tao WANG,Chao GAO,Jiren YUAN,Zhihao YUE,Lang ZHOU

期刊论文

基于正交质谱的N-糖组谱揭示哈夫病潜在病原学

刘思, 刘圆圆, 林佳静, 刘笔锋, 何振宇, 吴晓旻, 刘欣

期刊论文

Preparation and lithium storage performances of g-C

Zhengxu BIAN, Zehua TANG, Jinfeng XIE, Junhao ZHANG, Xingmei GUO, Yuanjun LIU, Aihua YUAN, Feng ZHANG, Qinghong KONG

期刊论文

Stability and dynamics of rotor system with 45° slant crack on shaft

Yanli LIN, Xiaohui SI, Fulei CHU

期刊论文

New practice in semaglutide on type-2 diabetes and obesity: clinical evidence and expectation

期刊论文